R&B artists Toni Braxton and Kenny "Babyface" Edmonds are reuniting.

The Grammy-award winners are teaming up for an upcoming album of duets called, "Love, Marriage & Divorce." The 45-year-old Braxton, 45, and the 54-year-old Babyface debuted "Hurt You," the first single off of the album on Monday morning.

The song showcases the veteran singers' pipes in an emotional slow-tempo track. "Here we go / Damn, here we go again / Loving you has caused me so much pain / But you don't see it, you never see it," Babyface croons in the song.

"The album celebrates the strong bond that has been in place between the two artists ever since Babyface and Toni's duet on her smash 1992 debut, 'Give U My Heart' which was co-written and co-produced by Babyface [from the 'Boomerang' movie soundtrack]," a news release said, according to the Untied Press International.

Braxton released her last studio album, "Pulse" in 2010. In the recent years, Braxton has appeared on the reality show, "Braxton Family Values" and has explored her talents in acting. Babyface released his last studio album, "Playlist," in 2007.

The album is good news for Braxton, who last week suffered a major wardrobe malfunction during a concert in New Jersey. As she was singing, her bare backside was suddenly on show for all to see.

"I was dancing doing the one-two and I kind of thought, 'Are my [breasts] exposed? I am feeling air," she tells Omg! Insider's Kevin Frazier. "I remember that distinctly, so that's why I held the top of the dress but then I realized the whole dress was coming apart. The whole dress just fell apart on stage!"

The singer was not completely bare; Braxton wore a bodysuit under her outfit. The singer called the experience embarrassing, and uncomfortable. But laughed it off, saying she should charged more for tickets.

"Hurt You," the first single from their new album, is currently on the radio and iTunes. The album is scheduled to hit stores on Dec. 3.

Take a listen to "Hurt You"