Seven years after being named Esquire Magazine's sexiest woman alive, Scarlett Johansson has been honored with the title for a second time, making her the first woman to wear the crown twice.

"I'm the only woman to win twice right?" the "Don Jon" actress asked the magazine. "You know, I gotta hustle. I'm a 28-year-old woman in the movies business, right? Pretty soon the roles you've offered all become mothers. Then they just sort of stop. I have to hedge against that with work-theater, producing; this thing with Esquire."

Johansson recently announced she's off the market; after becoming engaged to former French journalist Romain Dauriac. This will be her second marriage, after splitting from Ryan Reynolds in 2010. She said jealousy "comes with the territory" of being with a Frenchman.

"I didn't think I was a jealous person," she said, "until I started dating my current, my one-and-only. I think maybe in the past I didn't have the same kind of investment. Not that I liked my partner less, I just wasn't capable of it or caring that much."

Johansson has been in several high-profile relationships, romancing the likes of Sean Penn and Jared Leto, but the actress said she's excited to take the plunge again.

"I'm taking a month-long vacation," she said. " But I'm not going anywhere, which just makes it more of a staycation. There's luxury in being near home. When you spend a lot of time, like I do, just standing around and waiting, or being moved from place to place, every minute gets consumed by something someone else has set up for you.

The November issue of Esquire hits newsstands Oct. 15.